Derivatives of [n5-cyclopentadienyl]molybdenum tricarbonyl hydride and chloride, n5-C5H5Mo[CO]3X [X = hydrogen, chlorine], containing a bicyclic phosphorus-nitrogen ligand

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Embedding of N5 and the contiguous degrees

Downey and Lempp 8] have shown that the contiguous computably enumerable (c.e.) degrees, i.e. the c.e. Turing degrees containing only one c.e. weak truth-table degree, can be characterized by a local distributivity property. Here we extend their result by showing that a c.e. degree a is noncontiguous if and only if there is an embedding of the nonmodular 5-element lattice N5 into the c.e. degre...

Myeloperoxidase, hydrogen peroxide, chloride antimicrobial system: nitrogen-chlorine derivatives of bacterial components in bactericidal action against Escherichia coli.

In the presence of Escherichia coli, myeloperoxidase-catalyzed oxidation of chloride ion resulted in formation of long-lived chloramine and/or chloramide derivatives of bacterial components. The same amount of these nitrogen-chlorine (N-Cl) derivatives was obtained with either hypochlorous acid (HOCl) or the myeloperoxidase system, indicating that myeloperoxidase catalyzed the oxidation of chlo...

Cleavage of oligonucleotides containing a P3'→N5' phosphoramidate linkage mediated by single-stranded oligonucleotide templates.

Double-stranded DNA (dsDNA) templates can hybridize to and accelerate cleavage of oligonucleotides containing a P3'→N5' phosphoramidate (P-N) linkage. This dsDNA-templated cleavage of P-N linkages could be due to conformational strain placed on the linkage upon triplex formation. To determine whether duplex formation also induced conformational strain, we examined the reactivity of the oligonuc...

Chlorine activation indoors and outdoors via surface-mediated reactions of nitrogen oxides with hydrogen chloride.

Gaseous HCl generated from a variety of sources is ubiquitous in both outdoor and indoor air. Oxides of nitrogen (NO(y)) are also globally distributed, because NO formed in combustion processes is oxidized to NO(2), HNO(3), N(2)O(5) and a variety of other nitrogen oxides during transport. Deposition of HCl and NO(y) onto surfaces is commonly regarded as providing permanent removal mechanisms. H...